Z-Score for Real numbers:
Z = (X - Avg) / SD
The obvious approach that comes to mind, would be calculating the average & standard deviation for the real plane & imaginary plane independently.
Then we would presumably alter the formula, to use something like sqrt( sum-of-squares) approach to combine real & imaginary components or scores.
Zr = (Xr - AvgR) / SDr
Zi = (Xi - AvgI) / SDi
And finally:
Zc = sqrt( Zr^2 + Zi^2)
This would probably be the most straightforward way of producing a single Z-score from a complex number within it's distribution.
This is of course different from 'normalization', which would retain separate components and what was what I initially answered. But I believe that a single score, measuring distance from the mean, is what you're after here.