It looks like the Unirest code in Unirest.php relies on autoloading code from the two other files in the unirest lib directory (HttpMethod.php and HttpResponse.php).
The author suggests installing the package using composer, if you were to do that composer would add the Unirest namespace to the autoloader.php script it generates. From there you need to require the autoload.php file at the top of your script and it will handle loading classes that aren't defined.
Alternatively, if you don't want to use composer, I would just require the other two files in the unirest lib directory at the top of your script as well.